Construction of Functional Macromolecules with Well-Defined Structures by Indium-Catalyzed Three-Component Polycoupling of Alkynes, Aldehydes, and Amines
Identifieur interne : 001019 ( Main/Repository ); précédent : 001018; suivant : 001020Construction of Functional Macromolecules with Well-Defined Structures by Indium-Catalyzed Three-Component Polycoupling of Alkynes, Aldehydes, and Amines
Auteurs : RBID : Pascal:13-0232702Descripteurs français
- Pascal (Inist)
- Phénylèneéthynylène copolymère, Silane copolymère, Copolymère hétérocyclique, Phénylènevinylène dérivé copolymère, Amine copolymère, Copolymère insaturé, Polymère fonctionnel, Composé soluble, Matériau luminescent, Précurseur, Préparation, Polycondensation solution, Copolycondensation, Composé diynique, Dialdéhyde, Amine secondaire, Hétérocycle silicium, Stabilité thermique, Solution organique, Spectre absorption, Photoluminescence, Substitution coordinat, Cobalt Carbonyle Complexe, Indice réfraction, Pyrolyse, Céramique, Matériau magnétique, Courbe aimantation, Silole dérivé copolymère, Triphénylamine copolymère, Complexe métal polymère, Copolymère polyynique, Etude expérimentale.
- Wicri :
- concept : Céramique.
English descriptors
- KwdEn :
- Absorption spectrum, Amine copolymer, Ceramic materials, Cobalt Carbonyl Complexes, Copolycondensation, Dialdehyde, Diynic compound, Experimental study, Functional polymer, Heterocyclic copolymer, Ligand substitution, Luminescent material, Magnetic material, Magnetization curve, Organic solution, Phenyleneethynylene copolymer, Phenylenevinylene derivative copolymer, Photoluminescence, Precursor, Preparation, Pyrolysis, Refraction index, Secondary amine, Silane copolymer, Silicon heterocycle, Soluble compound, Solution polycondensation, Thermal stability, Unsaturated copolymer.
Abstract
We present here a new programmable polymerization route for the synthesis of new conjugated polymers via one-pot reaction route. The three-component polycoupling reactions of terephthalaldehyde and dibenzylamine with 4,4'-diethynyl-1,1'-biphenyl, bis(4-ethynylphenyl)dimethylsilane, 1,2-bis(4-ethynylphenyl)-1,2-diphenylethene, N,N-bis(4-ethynylphenyl)aniline, or 2,5-bis(4-ethynylphenyl)-1,1-dimethyl-3,4-diphenylsilole are catalyzed by indium(III) chloride in o-xylene at 140 °C, affording soluble polymers with well-defined structures and high molecular weights (Mw up to 51 200) in high yields (up to 96.9%). Model reaction was carried out to elucidate the chemical structures of the polymers. The resulting polymers are processable and enjoy high thermal stability. The polymers carrying tetraphenylethene and silole units are weakly emissive in solutions but become strong emitters when aggregated in poor solvents or fabricated as thin films in the solid state, displaying a phenomenon of aggregation-enhanced emission characteristic. Thin films of the polymers show high refractive indices (n = 1.7529-1.6041) in a wide wavelength region of 400-1600 nm with low optical dispersions (D' down to 0.005). The polymers are readily metallified by complexation of their triple bonds with cobalt octacarbonyls. Pyrolysis of the resulting organometallic polymers at high temperature under inert atmosphere generates nanostructured ceramics with high magnetic susceptibility (Ms up to 80.7 emu/g) and near-zero coercivity (Hc down to 0.19 kOe).
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Construction of Functional Macromolecules with Well-Defined Structures by Indium-Catalyzed Three-Component Polycoupling of Alkynes, Aldehydes, and Amines</title><author><name sortKey="Chan, Carrie Y K" uniqKey="Chan C">Carrie Y. K. Chan</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science and Technology (HKUST)</s1><s2>Clear Water Bay, Kowloon</s2><s3>HKG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Hong Kong</country><wicri:noRegion>Clear Water Bay, Kowloon</wicri:noRegion></affiliation></author><author><name sortKey="Tseng, Nai Wen" uniqKey="Tseng N">Nai-Wen Tseng</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science and Technology (HKUST)</s1><s2>Clear Water Bay, Kowloon</s2><s3>HKG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Hong Kong</country><wicri:noRegion>Clear Water Bay, Kowloon</wicri:noRegion></affiliation></author><author><name sortKey="Lam, Jacky W Y" uniqKey="Lam J">Jacky W. Y. Lam</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science and Technology (HKUST)</s1><s2>Clear Water Bay, Kowloon</s2><s3>HKG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Hong Kong</country><wicri:noRegion>Clear Water Bay, Kowloon</wicri:noRegion></affiliation></author><author><name>JIANZHAO LIU</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science and Technology (HKUST)</s1><s2>Clear Water Bay, Kowloon</s2><s3>HKG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Hong Kong</country><wicri:noRegion>Clear Water Bay, Kowloon</wicri:noRegion></affiliation></author><author><name sortKey="Kwok, Ryan T K" uniqKey="Kwok R">Ryan T. K. Kwok</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science and Technology (HKUST)</s1><s2>Clear Water Bay, Kowloon</s2><s3>HKG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Hong Kong</country><wicri:noRegion>Clear Water Bay, Kowloon</wicri:noRegion></affiliation></author><author><name>BEN ZHONG TANG</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science and Technology (HKUST)</s1><s2>Clear Water Bay, Kowloon</s2><s3>HKG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></inist:fA14><country>Hong Kong</country><wicri:noRegion>Clear Water Bay, Kowloon</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Guangdong Innovative Research Team, SCUT-HKUST Joint Research Laboratory, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology (SCUT)</s1><s2>Guangzhou 510640</s2><s3>CHN</s3><sZ>6 aut.</sZ></inist:fA14><country>République populaire de Chine</country><wicri:noRegion>Guangzhou 510640</wicri:noRegion></affiliation><affiliation wicri:level="1"><inist:fA14 i1="03"><s1>HKUST-Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park</s1><s2>Nanshan, Shenzhen 518057</s2><s3>CHN</s3><sZ>6 aut.</sZ></inist:fA14><country>République populaire de Chine</country><wicri:noRegion>Nanshan, Shenzhen 518057</wicri:noRegion></affiliation></author></titleStmt><publicationStmt><idno type="inist">13-0232702</idno><date when="2013">2013</date><idno type="stanalyst">PASCAL 13-0232702 INIST</idno><idno type="RBID">Pascal:13-0232702</idno><idno type="wicri:Area/Main/Corpus">000A83</idno><idno type="wicri:Area/Main/Repository">001019</idno></publicationStmt><seriesStmt><idno type="ISSN">0024-9297</idno><title level="j" type="abbreviated">Macromolecules : (Print)</title><title level="j" type="main">Macromolecules : (Print)</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectrum</term><term>Amine copolymer</term><term>Ceramic materials</term><term>Cobalt Carbonyl Complexes</term><term>Copolycondensation</term><term>Dialdehyde</term><term>Diynic compound</term><term>Experimental study</term><term>Functional polymer</term><term>Heterocyclic copolymer</term><term>Ligand substitution</term><term>Luminescent material</term><term>Magnetic material</term><term>Magnetization curve</term><term>Organic solution</term><term>Phenyleneethynylene copolymer</term><term>Phenylenevinylene derivative copolymer</term><term>Photoluminescence</term><term>Precursor</term><term>Preparation</term><term>Pyrolysis</term><term>Refraction index</term><term>Secondary amine</term><term>Silane copolymer</term><term>Silicon heterocycle</term><term>Soluble compound</term><term>Solution polycondensation</term><term>Thermal stability</term><term>Unsaturated copolymer</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Phénylèneéthynylène copolymère</term><term>Silane copolymère</term><term>Copolymère hétérocyclique</term><term>Phénylènevinylène dérivé copolymère</term><term>Amine copolymère</term><term>Copolymère insaturé</term><term>Polymère fonctionnel</term><term>Composé soluble</term><term>Matériau luminescent</term><term>Précurseur</term><term>Préparation</term><term>Polycondensation solution</term><term>Copolycondensation</term><term>Composé diynique</term><term>Dialdéhyde</term><term>Amine secondaire</term><term>Hétérocycle silicium</term><term>Stabilité thermique</term><term>Solution organique</term><term>Spectre absorption</term><term>Photoluminescence</term><term>Substitution coordinat</term><term>Cobalt Carbonyle Complexe</term><term>Indice réfraction</term><term>Pyrolyse</term><term>Céramique</term><term>Matériau magnétique</term><term>Courbe aimantation</term><term>Silole dérivé copolymère</term><term>Triphénylamine copolymère</term><term>Complexe métal polymère</term><term>Copolymère polyynique</term><term>Etude expérimentale</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Céramique</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">We present here a new programmable polymerization route for the synthesis of new conjugated polymers via one-pot reaction route. The three-component polycoupling reactions of terephthalaldehyde and dibenzylamine with 4,4'-diethynyl-1,1'-biphenyl, bis(4-ethynylphenyl)dimethylsilane, 1,2-bis(4-ethynylphenyl)-1,2-diphenylethene, N,N-bis(4-ethynylphenyl)aniline, or 2,5-bis(4-ethynylphenyl)-1,1-dimethyl-3,4-diphenylsilole are catalyzed by indium(III) chloride in o-xylene at 140 °C, affording soluble polymers with well-defined structures and high molecular weights (M<sub>w</sub> up to 51 200) in high yields (up to 96.9%). Model reaction was carried out to elucidate the chemical structures of the polymers. The resulting polymers are processable and enjoy high thermal stability. The polymers carrying tetraphenylethene and silole units are weakly emissive in solutions but become strong emitters when aggregated in poor solvents or fabricated as thin films in the solid state, displaying a phenomenon of aggregation-enhanced emission characteristic. Thin films of the polymers show high refractive indices (n = 1.7529-1.6041) in a wide wavelength region of 400-1600 nm with low optical dispersions (D' down to 0.005). The polymers are readily metallified by complexation of their triple bonds with cobalt octacarbonyls. Pyrolysis of the resulting organometallic polymers at high temperature under inert atmosphere generates nanostructured ceramics with high magnetic susceptibility (M<sub>s</sub> up to 80.7 emu/g) and near-zero coercivity (H<sub>c</sub> down to 0.19 kOe).</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0024-9297</s0></fA01><fA02 i1="01"><s0>MAMOBX</s0></fA02><fA03 i2="1"><s0>Macromolecules : (Print)</s0></fA03><fA05><s2>46</s2></fA05><fA06><s2>9</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Construction of Functional Macromolecules with Well-Defined Structures by Indium-Catalyzed Three-Component Polycoupling of Alkynes, Aldehydes, and Amines</s1></fA08><fA11 i1="01" i2="1"><s1>CHAN (Carrie Y. K.)</s1></fA11><fA11 i1="02" i2="1"><s1>TSENG (Nai-Wen)</s1></fA11><fA11 i1="03" i2="1"><s1>LAM (Jacky W. Y.)</s1></fA11><fA11 i1="04" i2="1"><s1>JIANZHAO LIU</s1></fA11><fA11 i1="05" i2="1"><s1>KWOK (Ryan T. K.)</s1></fA11><fA11 i1="06" i2="1"><s1>BEN ZHONG TANG</s1></fA11><fA14 i1="01"><s1>Department of Chemistry, Institute for Advanced Study, Institute of Molecular Functional Materials and Division of Biomedical Engineering, The Hong Kong University of Science and Technology (HKUST)</s1><s2>Clear Water Bay, Kowloon</s2><s3>HKG</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ><sZ>3 aut.</sZ><sZ>4 aut.</sZ><sZ>5 aut.</sZ><sZ>6 aut.</sZ></fA14><fA14 i1="02"><s1>Guangdong Innovative Research Team, SCUT-HKUST Joint Research Laboratory, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology (SCUT)</s1><s2>Guangzhou 510640</s2><s3>CHN</s3><sZ>6 aut.</sZ></fA14><fA14 i1="03"><s1>HKUST-Shenzhen Research Institute, No. 9 Yuexing 1st RD, South Area, Hi-tech Park</s1><s2>Nanshan, Shenzhen 518057</s2><s3>CHN</s3><sZ>6 aut.</sZ></fA14><fA20><s1>3246-3256</s1></fA20><fA21><s1>2013</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>13789</s2><s5>354000174795520050</s5></fA43><fA44><s0>0000</s0><s1>© 2013 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>31 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>13-0232702</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Macromolecules : (Print)</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>We present here a new programmable polymerization route for the synthesis of new conjugated polymers via one-pot reaction route. The three-component polycoupling reactions of terephthalaldehyde and dibenzylamine with 4,4'-diethynyl-1,1'-biphenyl, bis(4-ethynylphenyl)dimethylsilane, 1,2-bis(4-ethynylphenyl)-1,2-diphenylethene, N,N-bis(4-ethynylphenyl)aniline, or 2,5-bis(4-ethynylphenyl)-1,1-dimethyl-3,4-diphenylsilole are catalyzed by indium(III) chloride in o-xylene at 140 °C, affording soluble polymers with well-defined structures and high molecular weights (M<sub>w</sub> up to 51 200) in high yields (up to 96.9%). Model reaction was carried out to elucidate the chemical structures of the polymers. The resulting polymers are processable and enjoy high thermal stability. The polymers carrying tetraphenylethene and silole units are weakly emissive in solutions but become strong emitters when aggregated in poor solvents or fabricated as thin films in the solid state, displaying a phenomenon of aggregation-enhanced emission characteristic. Thin films of the polymers show high refractive indices (n = 1.7529-1.6041) in a wide wavelength region of 400-1600 nm with low optical dispersions (D' down to 0.005). The polymers are readily metallified by complexation of their triple bonds with cobalt octacarbonyls. Pyrolysis of the resulting organometallic polymers at high temperature under inert atmosphere generates nanostructured ceramics with high magnetic susceptibility (M<sub>s</sub> up to 80.7 emu/g) and near-zero coercivity (H<sub>c</sub> down to 0.19 kOe).</s0></fC01><fC02 i1="01" i2="X"><s0>001D09D02E</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Phénylèneéthynylène copolymère</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Phenyleneethynylene copolymer</s0><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Fenilenoetinileno copolimero</s0><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Silane copolymère</s0><s2>NK</s2><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Silane copolymer</s0><s2>NK</s2><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Silano copolímero</s0><s2>NK</s2><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Copolymère hétérocyclique</s0><s2>NK</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="ENG"><s0>Heterocyclic copolymer</s0><s2>NK</s2><s5>03</s5></fC03><fC03 i1="03" i2="X" l="SPA"><s0>Copolímero heterocíclico</s0><s2>NK</s2><s5>03</s5></fC03><fC03 i1="04" i2="X" l="FRE"><s0>Phénylènevinylène dérivé copolymère</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="ENG"><s0>Phenylenevinylene derivative copolymer</s0><s5>04</s5></fC03><fC03 i1="04" i2="X" l="SPA"><s0>Fenilenovinileno derivado copolímero</s0><s5>04</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Amine copolymère</s0><s2>NK</s2><s5>05</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Amine copolymer</s0><s2>NK</s2><s5>05</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Amina copolímero</s0><s2>NK</s2><s5>05</s5></fC03><fC03 i1="06" i2="X" l="FRE"><s0>Copolymère insaturé</s0><s2>NK</s2><s5>06</s5></fC03><fC03 i1="06" i2="X" l="ENG"><s0>Unsaturated copolymer</s0><s2>NK</s2><s5>06</s5></fC03><fC03 i1="06" i2="X" l="SPA"><s0>Copolímero insaturado</s0><s2>NK</s2><s5>06</s5></fC03><fC03 i1="07" i2="X" l="FRE"><s0>Polymère fonctionnel</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="ENG"><s0>Functional polymer</s0><s5>07</s5></fC03><fC03 i1="07" i2="X" l="SPA"><s0>Polímero funcional</s0><s5>07</s5></fC03><fC03 i1="08" i2="X" l="FRE"><s0>Composé soluble</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="ENG"><s0>Soluble compound</s0><s5>08</s5></fC03><fC03 i1="08" i2="X" l="SPA"><s0>Compuesto soluble</s0><s5>08</s5></fC03><fC03 i1="09" i2="X" l="FRE"><s0>Matériau luminescent</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="ENG"><s0>Luminescent material</s0><s5>09</s5></fC03><fC03 i1="09" i2="X" l="SPA"><s0>Material luminescente</s0><s5>09</s5></fC03><fC03 i1="10" i2="X" l="FRE"><s0>Précurseur</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="ENG"><s0>Precursor</s0><s5>10</s5></fC03><fC03 i1="10" i2="X" l="SPA"><s0>Precursor</s0><s5>10</s5></fC03><fC03 i1="11" i2="X" l="FRE"><s0>Préparation</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="ENG"><s0>Preparation</s0><s5>11</s5></fC03><fC03 i1="11" i2="X" l="SPA"><s0>Preparación</s0><s5>11</s5></fC03><fC03 i1="12" i2="X" l="FRE"><s0>Polycondensation solution</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="ENG"><s0>Solution polycondensation</s0><s5>12</s5></fC03><fC03 i1="12" i2="X" l="SPA"><s0>Policondensación solución</s0><s5>12</s5></fC03><fC03 i1="13" i2="X" l="FRE"><s0>Copolycondensation</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="ENG"><s0>Copolycondensation</s0><s5>13</s5></fC03><fC03 i1="13" i2="X" l="SPA"><s0>Copolicondensación</s0><s5>13</s5></fC03><fC03 i1="14" i2="X" l="FRE"><s0>Composé diynique</s0><s1>ENT</s1><s5>14</s5></fC03><fC03 i1="14" i2="X" l="ENG"><s0>Diynic compound</s0><s1>ENT</s1><s5>14</s5></fC03><fC03 i1="14" i2="X" l="SPA"><s0>Compuesto diínico</s0><s1>ENT</s1><s5>14</s5></fC03><fC03 i1="15" i2="X" l="FRE"><s0>Dialdéhyde</s0><s1>ENT</s1><s5>15</s5></fC03><fC03 i1="15" i2="X" l="ENG"><s0>Dialdehyde</s0><s1>ENT</s1><s5>15</s5></fC03><fC03 i1="15" i2="X" l="SPA"><s0>Dialdehído</s0><s1>ENT</s1><s5>15</s5></fC03><fC03 i1="16" i2="X" l="FRE"><s0>Amine secondaire</s0><s1>ENT</s1><s5>16</s5></fC03><fC03 i1="16" i2="X" l="ENG"><s0>Secondary amine</s0><s1>ENT</s1><s5>16</s5></fC03><fC03 i1="16" i2="X" l="SPA"><s0>Amina secundaria</s0><s1>ENT</s1><s5>16</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Hétérocycle silicium</s0><s1>ENT</s1><s5>17</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Silicon heterocycle</s0><s1>ENT</s1><s5>17</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Heterociclo silicio</s0><s1>ENT</s1><s5>17</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Stabilité thermique</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Thermal stability</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Estabilidad térmica</s0><s5>18</s5></fC03><fC03 i1="19" i2="X" l="FRE"><s0>Solution organique</s0><s5>19</s5></fC03><fC03 i1="19" i2="X" l="ENG"><s0>Organic solution</s0><s5>19</s5></fC03><fC03 i1="19" i2="X" l="SPA"><s0>Solución orgánica</s0><s5>19</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Spectre absorption</s0><s5>20</s5></fC03><fC03 i1="20" i2="X" l="ENG"><s0>Absorption spectrum</s0><s5>20</s5></fC03><fC03 i1="20" i2="X" l="SPA"><s0>Espectro de absorción</s0><s5>20</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>Photoluminescence</s0><s5>21</s5></fC03><fC03 i1="21" i2="X" l="ENG"><s0>Photoluminescence</s0><s5>21</s5></fC03><fC03 i1="21" i2="X" l="SPA"><s0>Fotoluminiscencia</s0><s5>21</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>Substitution coordinat</s0><s5>22</s5></fC03><fC03 i1="22" i2="X" l="ENG"><s0>Ligand substitution</s0><s5>22</s5></fC03><fC03 i1="22" i2="X" l="SPA"><s0>Sustitución ligando</s0><s5>22</s5></fC03><fC03 i1="23" i2="X" l="FRE"><s0>Cobalt Carbonyle Complexe</s0><s2>NC</s2><s2>NA</s2><s5>23</s5></fC03><fC03 i1="23" i2="X" l="ENG"><s0>Cobalt Carbonyl Complexes</s0><s2>NC</s2><s2>NA</s2><s5>23</s5></fC03><fC03 i1="23" i2="X" l="SPA"><s0>Cobalto Carbonilo Complejo</s0><s2>NC</s2><s2>NA</s2><s5>23</s5></fC03><fC03 i1="24" i2="X" l="FRE"><s0>Indice réfraction</s0><s5>25</s5></fC03><fC03 i1="24" i2="X" l="ENG"><s0>Refraction index</s0><s5>25</s5></fC03><fC03 i1="24" i2="X" l="SPA"><s0>Indice refracción</s0><s5>25</s5></fC03><fC03 i1="25" i2="X" l="FRE"><s0>Pyrolyse</s0><s5>26</s5></fC03><fC03 i1="25" i2="X" l="ENG"><s0>Pyrolysis</s0><s5>26</s5></fC03><fC03 i1="25" i2="X" l="SPA"><s0>Pirólisis</s0><s5>26</s5></fC03><fC03 i1="26" i2="X" l="FRE"><s0>Céramique</s0><s5>27</s5></fC03><fC03 i1="26" i2="X" l="ENG"><s0>Ceramic materials</s0><s5>27</s5></fC03><fC03 i1="26" i2="X" l="SPA"><s0>Cerámica</s0><s5>27</s5></fC03><fC03 i1="27" i2="X" l="FRE"><s0>Matériau magnétique</s0><s5>28</s5></fC03><fC03 i1="27" i2="X" l="ENG"><s0>Magnetic material</s0><s5>28</s5></fC03><fC03 i1="27" i2="X" l="SPA"><s0>Material magnético</s0><s5>28</s5></fC03><fC03 i1="28" i2="X" l="FRE"><s0>Courbe aimantation</s0><s5>30</s5></fC03><fC03 i1="28" i2="X" l="ENG"><s0>Magnetization curve</s0><s5>30</s5></fC03><fC03 i1="28" i2="X" l="SPA"><s0>Característica magnética</s0><s5>30</s5></fC03><fC03 i1="29" i2="X" l="FRE"><s0>Silole dérivé copolymère</s0><s2>NK</s2><s4>INC</s4><s5>32</s5></fC03><fC03 i1="30" i2="X" l="FRE"><s0>Triphénylamine copolymère</s0><s2>NK</s2><s4>INC</s4><s5>33</s5></fC03><fC03 i1="31" i2="X" l="FRE"><s0>Complexe métal polymère</s0><s4>INC</s4><s5>34</s5></fC03><fC03 i1="32" i2="X" l="FRE"><s0>Copolymère polyynique</s0><s4>INC</s4><s5>35</s5></fC03><fC03 i1="33" i2="X" l="FRE"><s0>Etude expérimentale</s0><s5>81</s5></fC03><fC03 i1="33" i2="X" l="ENG"><s0>Experimental study</s0><s5>81</s5></fC03><fC03 i1="33" i2="X" l="SPA"><s0>Estudio experimental</s0><s5>81</s5></fC03><fC07 i1="01" i2="X" l="FRE"><s0>Propriété optique</s0><s5>24</s5></fC07><fC07 i1="01" i2="X" l="ENG"><s0>Optical properties</s0><s5>24</s5></fC07><fC07 i1="01" i2="X" l="SPA"><s0>Propiedad óptica</s0><s5>24</s5></fC07><fC07 i1="02" i2="X" l="FRE"><s0>Propriété magnétique</s0><s5>29</s5></fC07><fC07 i1="02" i2="X" l="ENG"><s0>Magnetic properties</s0><s5>29</s5></fC07><fC07 i1="02" i2="X" l="SPA"><s0>Propiedad magnética</s0><s5>29</s5></fC07><fN21><s1>217</s1></fN21><fN44 i1="01"><s1>PSI</s1></fN44><fN82><s1>PSI</s1></fN82></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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